Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy p. 743 - 750 (1982)
Update date:2022-08-29
Topics:
Lutz, E. T. G.
Maas, J. H. van der
The sensitivity of the OH-vibration in saturated axial cyclohexanols for γ-alkyl substituents has been studied.It appears that axial γ-substituents considerably influence both, the frequency and the presence of the rotamers.Besides the OH-vibration proves to be sensitive to the type of α-alkyl substituent.At least two types of intramolecular interaction affect the OH-frequency: (i) repulsive lone pair ... β- and γ-alkyl interaction and (ii) β-methyl ... axial β-H interaction.
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