Regio- and diastereo-selectivity of the insertion of aldehydes into alkyne zirconocene complexes

DOI: 10.1016/0022-328X(95)05587-2

Source and publish data:

Journal of Organometallic Chemistry p. 95 - 108 (1995)

Update date:2022-08-11

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Authors:

Maier, Martin E.

Oost, Thorsten

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Article abstract of DOI:10.1016/0022-328X(95)05587-2

Insertion of aldehydes into alkyne-zirconocene complexes provides configurationally pure allyl alcohols in a one-pot procedure.In the case of unsymmetrical alkynes, the regioselectivity of the insertion process is high for terminal alkynes.With trimethyls

Full text of DOI:10.1016/0022-328X(95)05587-2

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