Journal of Organic Chemistry p. 2732 - 2736 (1992)
Update date:2022-08-10
Topics:
Rychnovsky, Scott D.
Mickus, Daniel E.
Cholesterol is ubiquitious in mammals and plays an important role in human health.The unique relationship between enantiomers make ent-cholesterol, the unnatural enantiomer of cholesterol, a valuable new probe of cholesterol function in biochemical systems.We report the first enantioselective total synthesis of ent-cholesterol.
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