Tetrahedron Letters p. 2031 - 2034 (1996)
Update date:2022-08-10
Topics:
Greck, Christine
Ferreira, Franck
Genet, Jean Pierre
The first syntheses of enantiomerically pure (2R, 3R) and (2S, 3S) 3-hydroxypipecolic acids 1 and 2 respectively, have been achieved from methyl 7-methyl-3-oxo-6-octenoate. Key steps involved asymmetric hydrogenation and electrophilic amination.
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