Synthesis p. 201 - 203 (1996)
Update date:2022-08-22
Topics:
Dehaen, Wim
Corens, David
L'Abbe, Gerrit
Anthracenes bearing a primary alkyl, ω-hydroxyalkyl, aryl or vinyl substituent at the 2-position are conveniently prepared by a copper-catalyzed Grignard reaction on 2,3-epoxy-1,2,3,4-tetrahydroanthracene, followed by dehydration - dehydrogenation of the resulting alcohols with tetrachloro-1,2-benzoquinone (o-chloranil).
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