Chirality Transfer in Stereoselective Synthesis. A Highly Stereocontrolled Synthesis of 22-Hydroxylated Steroid Side Chains via the -Wittig Rearrangement

DOI: 10.1021/jo00371a042

Source and publish data:

Journal of Organic Chemistry p. 4090 - 4092 (1986)

Update date:2022-08-11

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Authors:

Koreeda, Masato

Ricca, Daniel J.

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Article abstract of DOI:10.1021/jo00371a042

An efficient approach toward 22-oxygenated steroid side chains has been accomplished utilizing the <2,3>-Wittig rearrangement of the dianion derived from the (E)-17(20)-ethylidene-16α-(carboxymethyl)oxy steroid.

Full text of DOI:10.1021/jo00371a042

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