Rearrangement of 5-(bromomethyl)-1-pyrrolinium salts into functionalized piperidines

DOI: 10.1016/0040-4039(96)00487-X

Source and publish data:

Tetrahedron Letters p. 3171 - 3174 (1996)

Update date:2022-08-30

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Authors:

De Kimpe, Norbert

Boelens, Mark

Contreras, Jan

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Article abstract of DOI:10.1016/0040-4039(96)00487-X

5-(Bromomethyl)-1-pyrrolinium bromides undergo rearrangement with alkoxides in the corresponding alcohol to afford 2,5-dialkoxypiperidines, which are easily converted into 3-alkoxypiperidines. 2,5-Dialkoxypiperidines undergo a peculiar thermal rearrangeme

Full text of DOI:10.1016/0040-4039(96)00487-X

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