Tetrahedron p. 2225 - 2232 (1988)
Update date:2022-08-10
Topics:
Gupta, Kalyan Kali Sen
Kumar, Saroj Chandra
Sen, Pratik Kumar
Banerjee, Amalendu
The kinetics of oxidation of some substituted benzyl alcohols as well as the unsubstituted one by bromate ion in hydrochloric acid medium has been suggested.The results indicate that the reaction takes place by way of intermediate ester formation.Methoxy compounds react at much faster rates than the corresponding nitro substituted derivatives.The thermodynamic values associated with the equilibrium step and also for the slow step have been evaluated.A mechanism consistent with the experimental observations has been suggested.
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