Chemistry Letters p. 917 - 920 (1983)
Update date:2022-08-10
Topics:
Funabiki, Takuzo
Mizoguchi, Akira
Sugimoto, Tsunemi
Yoshida, Satohiro
Iron(III) complex coordinated by 2,2'-bipyridine and pyridine catalyzes oxygenation of 3,5-di-t-butylcatechol with molecular oxygen to give intra- and extradiol fission products as well as oxidation to give 3,5-di-t-butyl-1,2-benzoquinone.Structures and reactivities of the products have indicated that the oxygenation proceeds by the Hamilton process rather than the dioxetane process.
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Doi:10.1039/f19898501493
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