Tetrahedron Letters p. 9279 - 9282 (1996)
Update date:2022-08-30
Topics:
Fan, Yun-Hua
Haseltine, John
Hydrated acetaldehydes were condensed in D2O with substituted alcohols and thiols to determine ΔG of hemiacetalization by 1H NMR. Specific n→σ* delocalizalions in the alkoxy/alkylthio functionality of the product interact to influence n→σ* delocalization in the hemiacetal functionality. Delocalization in the latter functionality controls ΔG.
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