Component match in rhodium catalyzed three-component reactions of ethyl diazoacetate, H2O and aryl imines: A highly diastereoselective one-step synthesis of β-aryl isoserine derivatives

DOI: 10.1039/b915013g

Source and publish data:

Organic and Biomolecular Chemistry p. 5028 - 5033 (2009)

Update date:2022-08-11

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Authors:

Guo, Zhenqiu

Shi, Taoda

Jiang, Jun

Yang, Liping

Hu, Wenhao

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Article abstract of DOI:10.1039/b915013g

Water and ethyl diazoacetate were found to be matched components for generating highly reactive nucleophilic oxonium ylide in the presence of a dirhodium acetate catalyst. Simultaneous trapping of the oxonium ylide intermediate with aryl imines gave β-ary

Full text of DOI:10.1039/b915013g

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