Tetrahedron Letters p. 7771 - 7774 (1996)
Update date:2022-08-10
Topics:
Mori, Hajime
Ikoma, Keiichi
Masui, Yukio
Isoe, Sachihiko
Kitaura, Kazuo
Katsumura, Shigeo
In a significantly twisted 1,3-diene, a regio-selective ene-reaction of the vinyl hydrogen rather than the allyl hydrogen with singlet oxygen was observed, and this phenomena is rationalized by considering largo σ*-π orbital interactions between the vinyl
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