Abnormally high reactivity of the vinyl hydrogen toward singlet oxygen in a twisted 1,3-diene

DOI: 10.1016/0040-4039(96)01774-1

Source and publish data:

Tetrahedron Letters p. 7771 - 7774 (1996)

Update date:2022-08-10

Topics:

Authors:

Mori, Hajime

Ikoma, Keiichi

Masui, Yukio

Isoe, Sachihiko

Kitaura, Kazuo

Katsumura, Shigeo

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0040-4039(96)01774-1

In a significantly twisted 1,3-diene, a regio-selective ene-reaction of the vinyl hydrogen rather than the allyl hydrogen with singlet oxygen was observed, and this phenomena is rationalized by considering largo σ*-π orbital interactions between the vinyl

Full text of DOI:10.1016/0040-4039(96)01774-1

Products guided by the article

Product name:(1Z)-3-methyl-1-(2',2',6'-trimethylcyclohex-1'-enyl)-3-triethylsiloxy-1-butene

Cas No:185140-33-4

R&D Labs maybe for 185140-33-4

Shanghai UCHEM Inc.

Contact:+86-21-56338808

Address:799 Dunhuang Road, Putuo
Nanjing Vincero International Trading Co.,Ltd

Contact:8618936897229

Address:NO.68, ZhuShan Road, JiangNing WanDa Plaza, Building E Room 1703
Esuccess Material Limited

Contact:852-29282288

Address:HONGKONG
AUSHUN PHARMACEUTICAL TECHNOLOGY CO,.LTD

Contact:+86-25-86883560 15951806178

Address:14 Dayingbi, Zhujiang Rd. East, Nanjing, Jiangsu, China.
Second Pharma Co., Ltd

Contact:+86-575-82733999 0575-82732999

Address:hangzhou gulf fine chemical zone,shangyu city,zhejiang province

Relevant to this article

REAKTION VON TRIS(TRIMETHYLSILYL)ALUMINIUM MIT α, β-UNGESAETTIGTEN CARBONYLVERBINDUNGEN

Doi:10.1016/S0040-4039(00)81322-2
(1983)
KF-melamine formaldehyde resin (KF-MFR) as a versatile and efficient heterogeneous reagent for aldol condensation of aldehydes and ketones under microwave irradiation

Doi:10.1002/cjoc.201190227
(2011)
Methyl acetate synthesis by esterification on the modified ferrierite: Correlation of acid sites measured by pyridine IR and NH₃-TPD for steady-state activity

Doi:10.1166/jnn.2016.11013
(2016)
Synthesis, self-assembly, fluorescence, and thermosensitive properties of star-shaped amphiphilic copolymers with porphyrin core

Doi:10.1002/pola.24665
(2011)
Doi:10.1002/mpr.91
(1951)
Dependence of LC state on molecular flexibility

Doi:10.1080/15421406.2016.1146935
(2016)

Article Doi