Journal of the Chemical Society. Chemical communications p. 2535 - 2538 (1994)
Update date:2022-08-11
Topics:
Osa, Tetsuo
Kashiwagi, Yoshitomo
Yanagisawa, Yoshinori
Bobbitt, James M.
Constant potential electrolysis of 2-naphthol, 2-methoxynaphthalene and 10-hydroxyphenanthrene at 0.6 V vs.Ag/AgCl on a TEMPO-modified graphite felt electrode in the presence of (-)-sparteine in acetonitrile yields, enantioselectively, (S)-binaphthyl type dimers in > 92percent isolated yield and with > 88percent current efficiency with enantiomeric excess of 98, 91 and 97percent respectively for each dimer, respectively.
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