Recueil des Travaux Chimiques des Pays-Bas p. 348 - 352 (1992)
Update date:2022-08-29
Topics:
Verhart, Cor G. J.
Caris, Brigitte M. G.
Zwanenburg, Binne
Chittenden, Gordon J. F.
An efficient cleavage-isopropylidenation reaction of sucrose, catalyzed by iodine, is described.Related D-fructofuranosyl-containing oligosaccharides and their individual monosaccharide units were treated in a similar manner to yield isopropylidenated monosaccharide derivatives.The reaction conditions are particularly mild and selective.Some mechanistic aspects of the procedure are also discussed.
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