Reaction of the aromatic olefin 1-(1-hexenyl)-2-thiomethylbenzene with Cp2Zr(H)Cl. Unexpected cleavage of the methyl-sulphur bond

DOI: 10.1016/0022-328X(89)85407-5

Source and publish data:

Journal of Organometallic Chemistry p. 295 - 302 (1989)

Update date:2022-08-17

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Authors:

Annby, Ulf

Gronowitz, Salo

Hallberg, Anders

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Article abstract of DOI:10.1016/0022-328X(89)85407-5

Reaction of the aromatic olefin 1-(1-hexenyl)-2-thiomethylbenzene with Cp2Zr(H)Cl results in cleavage of the sulphur-methyl bond.When the 2-hexylthiophenol thus formed is exposed to air, it is oxidized to the corresponding disulphide, which is produced in

Full text of DOI:10.1016/0022-328X(89)85407-5

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