Journal of Organometallic Chemistry p. 87 - 106 (1982)
Update date:2022-08-03
Topics:
Barton, Thomas J.
Goure, William F.
Witiak, Joanne L.
Wulff, William D.
Evidence for a radical mechanism in the termal decomposition of a 7-silanorbornadiene is presented.It is demonstrated that 2-carboxy-7-silanorbornadienes undergo a formal 1,5-migration of silicon to form O-silyl enol ethers.An earlier suggested rearrangement of a 7-silanorbornadiene to a silepin or silanorcardiene is excluded.A recent report of thermal and photochemical epimerization of 7-silanorbornadienes is shown to be incorrect.
View MoreJintan City Mego Chemical Co., Ltd
Contact:+86-0519-82814387
Address:23# Dengguan Town, Jintan, Jiangsu Province, China
ShangHai Ruiyi Medical Technology Co.,Ltd.
Contact:+86-21-54718086
Address:No951 Jianchuan RD，Minhang District
Beijing Tianjia Chemical Science & Technology Co.,Ltd
Contact:86-0550-2392698
Address:No.388, Shiliang Road (East),
Lishui Nanming Chemical Co., Ltd(expird)
Contact:+86-0578-2134101，2697830
Address:No.19 Tongji Road Shuige Industrial zone
Lyrin Industrial Corporation Limited
Contact:86-731-82571800
Address:Rm 2408,Asia Economy International Building,Shaoshan Road South,Yuhua District,Changsha,Hunan,China
Doi:10.1149/1.1394038
(2000)Doi:10.1016/j.ejmech.2011.12.038
(2012)Doi:10.1016/j.bmcl.2012.01.059
(2012)Doi:10.1016/j.bmc.2012.02.018
(2012)Doi:10.1016/0957-4166(94)80072-3
(1994)Doi:10.1021/jm201402v
(2012)
