Journal of Organometallic Chemistry p. 87 - 106 (1982)
Update date:2022-08-03
Topics:
Barton, Thomas J.
Goure, William F.
Witiak, Joanne L.
Wulff, William D.
Evidence for a radical mechanism in the termal decomposition of a 7-silanorbornadiene is presented.It is demonstrated that 2-carboxy-7-silanorbornadienes undergo a formal 1,5-migration of silicon to form O-silyl enol ethers.An earlier suggested rearrangement of a 7-silanorbornadiene to a silepin or silanorcardiene is excluded.A recent report of thermal and photochemical epimerization of 7-silanorbornadienes is shown to be incorrect.
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