Journal of the Chemical Society. Chemical communications p. 348 - 349 (1986)
Update date:2022-08-17
Topics:
Butler, John
Land, Edward J.
Pruetz, Walter A.
Swallow, A. John
Whereas tryptophan radicals oxidise tyrosine over a wide range of pH values, the one-electron reduction potential of the electron-deficient tryptophan radical at pH 7 is only 0.093 V more positive than that of the corresponding tyrosine radical, so that the reaction proceeds in reverse in strongly acid and alkaline solution.
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