Diastereoselective Hydroxylation of Titanium Enolates with tert-Butylhydroperoxide

DOI: 10.1016/0040-4020(95)00090-U

Source and publish data:

Tetrahedron p. 3175 - 3180 (1995)

Update date:2022-08-11

Topics:

Authors:

Schulz M.

Kluge, R.

Schuessler, M.

Hoffmann, G.

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Article abstract of DOI:10.1016/0040-4020(95)00090-U

The oxidation of titanium enolates with tert-butylhydroperoxide has been investigated and the main reaction products, the corresponding α-hydroxyketones 7a-f, isolated.The highest diastereoselectivities (>95percent de) were obtained, when titanium enolates of camphor 2d-6d were employed.For comparison, the oxidation of the enolates with dimethyldioxirane is discussed.

Full text of DOI:10.1016/0040-4020(95)00090-U

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