Journal of the American Chemical Society p. 4815 - 4817 (1988)
Update date:2022-08-29
Topics:
Toru, Takeshi
Yamada, Yoshio
Ueno, Toshio
Maekawa, Eturo
Ueno, Yoshio
A new, mild, and efficient method for the construction of the prostanoid skeleton involving cuprate addition to α-(phenylseleno)cyclopentenones followed by radical-based coupling to the resulting products with allylstannane derivatives is described.The method is applied to the synthesis of 6-oxoprostaglandin E1, a biologically active and naturally occurring compound.
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