Journal of Fluorine Chemistry p. 57 - 74 (1981)
Update date:2022-08-02
Topics:
Feast, W. J.
Morland, J. B.
The evidence for the involvement of sigmatropic fluorine migrations in the isomerizations of fluorinated polyenes is reviewed and the difficulties inherent in providing satisfactory rationalizations are discussed.The thermal isomerizations of heptafluorocyclohexadienes under various reaction conditions are described.It is established that such isomerizations occur by a mechanism which does not involve catalysis by fluoride ion, however the exact mechanistic pathway remains uncertain.
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