Journal of the Chemical Society - Faraday Transactions p. 2379 - 2382 (1991)
Update date:2022-08-30
Topics:
Wallington, Timothy J.
Fourier-transform infrared spectroscopy was used to establish methyl hydroperoxide as the dominant product of the gas-phase reaction of methylperoxy radicals with hydroperoxy radicals.Over the pressure range 15-700 torr of either air or oxygen, 92 +/- 5percent of the reaction of CH3O2 with HO2 proceeds via channel (1a): CH3O2 + HO2 -> CH3OOH + O2 (1a).Quoted errors represent 2?.This result is discussed with respect to previous kinetic and mechanistic studies of peroxy radicals and computer models of atmospheric chemistry.
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