Reduction of CO2 by the 19 Electron Complexes FeI(cp)L3 5-cyclopentadienyl; L3=C6H6, C6Me6, or (PMe3)3>

DOI: 10.1039/c39890000812

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Journal of the Chemical Society. Chemical communications p. 812 - 813 (1989)

Update date:2022-08-18

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Authors:

Ruiz, Jaime

Guerchais, Veronique

Astruc, Didier

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Article abstract of DOI:10.1039/c39890000812

The 19 electron complexes I(cp)(C6R6)>, R=H (1) or Me (2), cp = η⁵-C5H5, reduce CO2 in tetrahydrofuran to give II(cp)(C6R6)>⁺, 1/2 CO3^2-, and 1/2 CO; in the presence of PMe3 and Na⁺PF

Full text of DOI:10.1039/c39890000812

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