Photoreduction of α-ketoamides; cyclization of unsaturated captodative radicals

DOI: 10.1016/S0040-4039(00)76753-0

Source and publish data:

Tetrahedron Letters p. 1541 - 1544 (1994)

Update date:2022-08-11

Topics:

Authors:

Cossy, Janine

Madaci, Abdelaziz

Pete, Jean-Pierre

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Article abstract of DOI:10.1016/S0040-4039(00)76753-0

When N-allyl α-ketoamides are irradiated in the presence of t-amines, a reductive photocyclization to hydroxypyrrolidones is observed. The reaction involves cyclization of an unsaturated captodative radical.

Full text of DOI:10.1016/S0040-4039(00)76753-0

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