The kinetics of acid-catalyzed decomposition of decanepersulfonic acid

DOI: 10.1007/BF02494430

Source and publish data:

Russian Chemical Bulletin p. 201 - 202 (1999)

Update date:2022-08-16

Topics:

Authors:

Zaripov Zaripov

Mukhametzyanova

Safiullin

Komissarov

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Article abstract of DOI:10.1007/BF02494430

The kinetics of thermal decomposition of decanepersulfonic acid (RSO₂OOH, R = C₁₀H₂₁) in CCl₄ in the presence of cyclohexanesulfonic and trifluoroacetic acids at 323-343 K was studied. The reaction has an autocatalytic character. The kinetics of consumption of the persulfonic acid is described by the equation -d[RSO₂OOH]/df = k₁[RSO₂OOH] + k₂[RSO₂OOH] · [HX].

Full text of DOI:10.1007/BF02494430

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