
Russian Chemical Bulletin p. 201 - 202 (1999)
Update date:2022-08-16
Topics:
Zaripov
Mukhametzyanova
Safiullin
Komissarov
The kinetics of thermal decomposition of decanepersulfonic acid (RSO2OOH, R = C10H21) in CCl4 in the presence of cyclohexanesulfonic and trifluoroacetic acids at 323-343 K was studied. The reaction has an autocatalytic character. The kinetics of consumption of the persulfonic acid is described by the equation -d[RSO2OOH]/df = k1[RSO2OOH] + k2[RSO2OOH] · [HX].
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