Journal of Organometallic Chemistry p. C13-C16 (1985)
Update date:2022-08-17
Topics:
Ladoulis, Sandra J.
Nicholas, Kenneth M.
Diiron nonacarbonyl has been found to promote the catalytic coupling of allylic acetates with malonate ion in good yields. Preliminary results on the regioselectivity of these reactions argue against a mechanism involving direct nucleophilic attack on either (η3-allyl)Fe(CO)4+ or (η2-allyl acetate)Fe(CO)4 complexes.
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