
Tetrahedron Letters p. 1885 - 1888 (1997)
Update date:2022-08-11
Topics:
Vaughan, William S.
Gu, Henry H.
McDaniel, Keith F.
Nucleophilic attack on tetracarbony (π-allyl)manganese takes place at the terminus of the π-system, generating allylated products in 44-95% yield after oxidation. Stabilized nucleophiles (pK(a) 12-20) give mainly bis allylation whereas nonstabilized nucleophiles (pKa 25-35) give mono allylation.
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