Zinc cyanamide, Zn(CN2)

DOI: 10.1107/S0108270101000865

Source and publish data:

Acta Crystallographica, Section C: Crystal Structure Communications p. 347 - 348 (2001)

Update date:2022-08-24

Topics:

Authors:

Becker, Michael

Jansen, Martin

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Article abstract of DOI:10.1107/S0108270101000865

Single crystals of the title compound have been grown by annealing microcrystalline zinc cyanamide at 843 K in silver crucibles. Zn(CN₂) crystallizes as colourless prisms. The crystal structure is composed of corner-linked ZnN_4/2 tetrahedra. Carbon and nitrogen form (CN₂)^2- dumb-bells with the C atom on a twofold axis. Nitrogen is approximately trigonally planar, coordinated by two Zn atoms and one C atom.

Full text of DOI:10.1107/S0108270101000865

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