Journal of the Chemical Society. Perkin transactions II p. 595 - 600 (1984)
Update date:2022-08-29
Topics:
Yano, Yumihiko
Sakaguchi, Terukiyo
Nakazato, Michiaki
The reduction of p-chloronitrobenzene by a reduced flavin has been investigated kinetically in the presence of divalent metal ions in EtOH under anaerobic conditions.A large rate acceleration due to the metal ions was observed; 1(none) : 32 Zn(2+) : 420 Ni(2+) : 1 000 Co(2+) : 12 Mn(2+).The role of the metal ions is proposed.The reducing ability of metal-chelated flavin radicals has been briefly examined by employing 2,4-dinitrochlorobenzene as an electron acceptor.
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