Chemical Communications p. 2459 - 2460 (1996)
Update date:2022-08-17
Topics:
Radu, Nora S.
Hollander, Frederick J.
Tilley, T. Don
Rheingold, Arnold L.
The samarium complex Cp*2SmCH(SiMe3)2 (Cp* = C5Me5), unlike the related alkyls Cp*2LnCH(SiMe3)2 (Ln = Y, Nd), mediates the redistribution of hydrosilanes while being converted to trisamarium clusters, including Cp*6Sm3(μ-SiH3)(μ 3-η1,η1,η2-SiH 2-SiH2).
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