Journal of Organic Chemistry p. 7195 - 7196 (1994)
Update date:2022-08-17
Topics:
Kulasegaram, Sanjitha
Kulawiec, Robert J.
Palladium(0)-tertiary phosphine complexes catalyze the chemo- and regioselective isomerization of epoxides to carbonyl compounds in good to excellent yields; alkyl-substituted epoxides afford methyl ketones, and aryl-substituted epoxides form aldehydes or ketones via cleavage of the benzylic C-O bond.
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