Efficient transformations of aldehydes and ketones into one-carbon homologated carboxylic acids

DOI: 10.1055/s-1996-4424

Source and publish data:

Synthesis p. 1425 - 1427 (1996)

Update date:2022-08-10

Topics:

Authors:

Katritzky, Alan R.

Toader, Dorin

Xie, Linghong

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Article abstract of DOI:10.1055/s-1996-4424

Peterson olefination of aldehydes and ketones with trimethylsilyl(methoxy)(benzotriazol-1-yl)methyl anion 6 afforded 1-(benzotriazol-1-yl)-1-methoxyalk-1-enes 7 which were treated without isolation with zinc bromide and hydrochloric acid, to yield the corresponding one-carbon homologated carboxylic acids 4 in good overall yields.

Full text of DOI:10.1055/s-1996-4424

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