Tetrahedron Letters p. 397 - 398 (1999)
Update date:2022-08-25
Topics:
Sarkar, Tarun K.
Ghosh, Sunil K.
Nandy, Sandip K.
Chow, Tahsin J.
The title compound, an intermediate in the Hamaguchi-Ibata reaction involving the Rh(II)-catalysed intramolecular reaction of a diazo group with the carbonyl of an adjacent amido group has been isolated and characterized. PM3 calculations reveal the heat of formation(ΔH(f)) of this remarkably stable molecule to be -77.69 kcal/mol.
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