Thermally induced and transition metal catalyzed aza-Claisen rearrangement of 2-cyclopropylideneethyl imidates: A new entry to 1-aminocyclopropanecarboxylic acids

DOI: 10.1016/0040-4039(95)00380-U

Source and publish data:

Tetrahedron Letters p. 2975 - 2977 (1995)

Update date:2022-08-17

Topics:: Authors:

Estieu, Karine

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Article abstract of DOI:10.1016/0040-4039(95)00380-U

(2-Cyclopropylideneethyl) acetimidates underwent thermally induced or palladium (II) catalyzed azaClaisen rearrangement into 1-ethenylcyclopropyl acetamides, providing convenient precursors to 1-amino cyclopropanecarboxylic acids (ACCs). Due to the regioselectivity of the nucleophilic substitution of the π 1,1-dimethylene allyl palladium complexes by soft nucleophiles, the palladium (0) catalysis was apparently non effective.

Full text of DOI:10.1016/0040-4039(95)00380-U

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Article Doi

Thermally induced and transition metal catalyzed aza-Claisen rearrangement of 2-cyclopropylideneethyl imidates: A new entry to 1-aminocyclopropanecarboxylic acids

DOI: 10.1016/0040-4039(95)00380-U

Source and publish data:

Authors:

Article abstract of DOI:10.1016/0040-4039(95)00380-U

Full text of DOI:10.1016/0040-4039(95)00380-U

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