OXIDATION WITH SODIUM PEROXIDE. DIRECT INTRODUCTION OF A γ CARBONYL GROUP INTO α,β UNSATURATED KETOSTEROIDS

DOI: 10.1016/S0040-4039(01)92437-2

Source and publish data:

Tetrahedron Letters p. 5127 - 5128 (1981)

Update date:2022-08-17

Topics:

Authors:

Holland, Herbert L.

Daum, Ulrich

Riemland, Elly

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Article abstract of DOI:10.1016/S0040-4039(01)92437-2

Aqueous sodium peroxide oxidises the conjugated Δ⁴-3-ketosteroids 1a-1d to the corresponding Δ⁴-3,6-diones in good yield.Saturated carbonyl and alcohol groups are not affected by the reaction.

Full text of DOI:10.1016/S0040-4039(01)92437-2

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