OXIDATION WITH SODIUM PEROXIDE. DIRECT INTRODUCTION OF A γ CARBONYL GROUP INTO α,β UNSATURATED KETOSTEROIDS

DOI: 10.1016/S0040-4039(01)92437-2

Source and publish data:

Tetrahedron Letters p. 5127 - 5128 (1981)

Update date:2022-08-17

Topics:

Authors:

Holland, Herbert L.

Daum, Ulrich

Riemland, Elly

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0040-4039(01)92437-2

Aqueous sodium peroxide oxidises the conjugated Δ⁴-3-ketosteroids 1a-1d to the corresponding Δ⁴-3,6-diones in good yield.Saturated carbonyl and alcohol groups are not affected by the reaction.

Full text of DOI:10.1016/S0040-4039(01)92437-2

Products guided by the article

Product name:Androst-4-ene-3,6,17-trione

Cas No:2243-06-3

R&D Labs maybe for 2243-06-3

AURORA CHEMICAL CO., LTD

Contact:86-532-68629711 13780605697

Address:NO 220 YANAN 3 ROAD,(POST ADMINISTRATION BUILDING),QINGDAO,CHINA
Huzhou City Linghu Xinwang Chemical Co.,Ltd.

Contact:86-572-3948695/3945236

Address:huzhou
Changzhou Anyi Biochem Co., Ltd.(expird)

Contact:+86-519-88836158

Address:no,51 caoda
Baoding City Light Industry And Textiles Imp.& Exp. Corp. Chemical Department.

Contact:86-312-3262436

Address:NO.658 CHAOYANG SOUTH STREET,BAODING CITY HEBEI CHINA
Nantong LiKai Chemical Co.,Ltd

Contact:+86-513-89068669

Address:Jincheng Science Park

Relevant to this article

A facile approach to spirocyclic 2-azido indolines via azidation of indoles with ceric ammonium nitrate

Doi:10.1039/c4ob01549e
(2014)
Acid-catalyzed isomerization of pivalaldehyde to methyl isopropyl ketone via a reactive protosolvated carboxonium ion intermediate

Doi:10.1021/ja011253a
(2001)
Samarium diiodide mediated coupling of 2-pyridylsulfonyl furanosides with aldehydes and ketones: A general synthesis of C-furanosides

Doi:10.1002/ejoc.201403640
(2015)
Synthesis of 1-alkynyl(diphenyl)onium salts of group 16 elements via heteroatom transfer reaction of 1-alkynyl(phenyl)-λ³-iodanes

Doi:10.1039/b212512a
(2003)
Kinetic and thermodynamic selectivity in subcomponent substitution

Doi:10.1002/chem.200601693
(2007)
Dual Farnesoid X Receptor/Soluble Epoxide Hydrolase Modulators Derived from Zafirlukast

Doi:10.1002/cmdc.201900576
(2020)

Article Doi