HOMOGENEOUS CATALYSIS OF MIXED-METAL SYSTEMS. HIGHLY REGIOSELECTIVE HYDROFORMYLATION-AMIDOCARBONYLATION OF A FLUORO OLEFIN CATALYZED BY Co-Rh MIXED-METAL SYSTEMS. OBSERVATION OF CoRh(CO)7 CATALYSIS.

Article abstract of DOI:10.1021/ja00209a024

The hydroformylation-amidocarbonylation of a fluoro olefin, C//6F//5CH equals CH//2, catalyzed by Co//2(CO)//8-rhodium carbonyl systems proceeds with excellent regioselectivity. The process includes a unique Co-Rh mixed-metal complex, CoRh(CO)//7, as an a