Implication of a Common Trimethylenemethane Intermediate in Dimer Formation and Structural Methylenecyclopropane Rearrangement of a Bicyclohex-1-ene to a 5-alkylidenebicyclopentane

DOI: 10.1021/ja00372a020

Source and publish data:

Journal of the American Chemical Society p. 2228 - 2232 (1982)

Update date:2022-08-11

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Authors:

Salinaro, Richard F.

Berson, Jerome A.

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Article abstract of DOI:10.1021/ja00372a020

Stereospecifically labelled 2,6,6-trimethylbicyclo<3.1.0>hex-1-ene (17b), generated by α-elimination from 1,1-dibromo-6-trans-trideuteriomethylhepta-1,5-diene (8b), dimerizes to stereospecifically labelled and products, 15b and 16b, and to

Full text of DOI:10.1021/ja00372a020

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