Bulletin of the Chemical Society of Japan p. 2357 - 2360 (1985)
Update date:2022-08-29
Topics:
Ishibashi, Masami
Tsuyuki, Takahiko
Takahashi, Takeyoshi
Ailanthone was converted into shinjulactone C with a hexacyclic 1α,12α:5α,13α-dicyclo-9βH-picrasane skeleton.The key reaction consists of an intramolecular ionic <4+2> cycloaddition between a pentadienyl cation and an olefin.
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