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Oxidation methods for aromatic diazines: Substituted pyrazine-N-oxides, pyrazine-N,N′-dioxides, and 2,2′:6′,2″-terpyridine-1,1″-dioxide

DOI: 10.1515/HC.2001.7.4.307

Source and publish data:

Heterocyclic Communications p. 307 - 312 (2001)

Update date:2022-08-23

Topics:

Authors:

McKay, Scott E.McKay, Scott E.

Sooter, Joseph A.Sooter, Joseph A.

Bodige, Satish G.Bodige, Satish G.

Blackstock, Silas C.Blackstock, Silas C.

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Article abstract of DOI:10.1515/HC.2001.7.4.307

In the course of investigations into the intermolecular interactions of azaaromatic N-oxides it was necessary to perform oxidations of the pyridine and pyrazine moieties. Generally, it was found that direct oxidation with OXONE gave efficient preparation of pyrazine dioxides. Oxidation with dimethyldioxirane was used to preclude problems associated with the isolation of particularly hydrophilic pyrazine and pyrazine-N-oxides.

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Full text of DOI:10.1515/HC.2001.7.4.307

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Brought to you by | New York University Elmer Holmes Bobst Library  
Authenticated  
Download Date | 10/2/14 12:56 PM  
Brought to you by | New York University Elmer Holmes Bobst Library  
Authenticated  
Download Date | 10/2/14 12:56 PM  
Brought to you by | New York University Elmer Holmes Bobst Library  
Authenticated  
Download Date | 10/2/14 12:56 PM  
Brought to you by | New York University Elmer Holmes Bobst Library  
Authenticated  
Download Date | 10/2/14 12:56 PM  

Products guided by the article

Product name:Pyrazine, tetramethyl-, 1-oxide (8CI,9CI)

Cas No:22978-83-2

22978-83-2

R&D Labs maybe for 22978-83-2

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