Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 684 - 687 (1990)
Update date:2022-08-10
Topics:
Feshin, V. P.
Dolgushin, G. V.
Voronkov, M. G.
Gaek, M.
Yanoushek, Z.
In molecules in the series Cl3CCH2CClRR', the substituents R and R' virtually do not affect the chlorine atoms of the Cl3C group, while the NQR frequency of the chlorine atom of the CClRR' group correlates satisfactorily with the ?* constants of these substituents.The regularities observed in the mutual influence of the atoms in the molecules of the studied series indicate that the previously assumed structure of some products of radical telomerization of Cl3CH with H2C=CHCl is erroneous.
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