Organocobaloxime in organic synthesis: efficient trapping of 5-phenylpent-4-ynyl radical by useful functional groups

DOI: 10.1016/0022-328X(94)87279-1

Source and publish data:

Journal of Organometallic Chemistry p. 233 - 238 (1994)

Update date:2022-08-29

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Authors:

Das, Indira

Roy, Sujit

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Article abstract of DOI:10.1016/0022-328X(94)87279-1

5-Phenylpent-4-ynyl cobaloxime, R(Co^III) reacts with the free radical precursors XY under thermal or photochemical conditions to give the corresponding organic product RX or RY, depending on the precursor.A non-chain radical mechanism is invoked to account for the product distribution. Key words: Cobaloxime; Radical

Full text of DOI:10.1016/0022-328X(94)87279-1

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