Tetrahedron Letters p. 1795 - 1798 (1992)
Update date:2022-08-29
Topics:
Lissel
Jansen In De Wal
Neumann
The H5PV2Mo10O40 heteropolyanion has been found to catalyse the highly selective aerobic oxidation of dialkylphenols to diphenoquinones and the oxidation of 2,3,5-trimethylphenol to the 2,3,5-trimethyl-1,4-benzoquinone. The rate is highly dependent on the oxidation potential of the substrate and is proceeds by electron transfer from the phenol substrate to the heteropolyanion catalyst.
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