Russian Chemical Bulletin p. 2086 - 2090 (1999)
Update date:2022-08-18
Topics:
Bredikhin
Pashagin
Strunskaya
Gubaydullin
Litvinov
Bredikhina
2,3-Epoxy alcohols (glycidols) react with carboxylic acid dichlorides to form cyclic esters of 3-chloro-1,2-diols. The reaction proceeds with complete retention of the configuration of the C(2) atom of the initial glycidol and with predominant (but not complete) inversion of the configuration of the C(3) atom in the final heterocycle.
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