New reaction of glycidols with oxalyl chloride and phosgene - An approach to cyclic esters

DOI: 10.1007/BF02494853

Source and publish data:

Russian Chemical Bulletin p. 2086 - 2090 (1999)

Update date:2022-08-18

Topics:

Authors:

Bredikhin

Pashagin

Strunskaya

Gubaydullin

Litvinov

Bredikhina

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Article abstract of DOI:10.1007/BF02494853

2,3-Epoxy alcohols (glycidols) react with carboxylic acid dichlorides to form cyclic esters of 3-chloro-1,2-diols. The reaction proceeds with complete retention of the configuration of the C(2) atom of the initial glycidol and with predominant (but not complete) inversion of the configuration of the C(3) atom in the final heterocycle.

Full text of DOI:10.1007/BF02494853

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