Journal of the Chemical Society. Chemical communications p. 1761 - 1762 (1994)
Update date:2022-08-23
Topics:
Nagakari, Mitsuhiro
Kushiro, Tetsuo
Yagi, Tomoko
Tanaka, Nobukazu
Matsumoto, Takeshi
et al.
<3α-2H>-, <4α-2H>- and <4β-2H>-Cholesterols and <3α-2H>- and <5-2H>-3β-hydroxy-5β-cholest-7-en-6-ones were converted with a hairy root culture of Ajuga reptans var. atropurpurea into 20-hydroxyecdysone, in which the deuterium atoms retained their original positions, thus strongly suggesting that 3β-hydroxy-5β-cholest-7-en-6-one is an obligatory intermediate in the biosynthesis of ecdysteroids in the plant.
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