Selective Palladium Catalysed Monohydroesterification of Diols

DOI: 10.1039/c39840001349

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1349 - 1351 (1984)

Update date:2022-08-11

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Authors:

Fergusson, Stuart B.

Alper, Howard

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Article abstract of DOI:10.1039/c39840001349

Olefins react with diols (e. g. ethylene glycol) under oxidative carbonylation and acidic conditions, using palladium and copper(II) chloride as catalysts, to give hydroxy esters in good yields; this mild reaction (room temperature, 1 atm) is a regioselective one.

Full text of DOI:10.1039/c39840001349

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