Facile Production of D-Histidine by Asymmetric Transformation of L-Histidine

DOI: 10.1246/bcsj.64.3741

Source and publish data:

Bulletin of the Chemical Society of Japan p. 3741 - 3742 (1991)

Update date:2022-08-11

Topics:

Authors:

Shiraiwa, Tadashi

Shinjo, Kazuyuki

Masui, Yoko

Ohta, Atsushi

Natsuyama, Hisashi

et. al. et. al.

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Article abstract of DOI:10.1246/bcsj.64.3741

An asymmetric transformation from L-histidine to D-His was achieved by using salicylaldehyde as a catalyst for epimerization, and (2R,3R)-tartaric acid as a resolving agent, in acetic acid.Treatment of the obtained salt with triethylamine in methanol gave D-His with 100percent optical purity in 95percent yield based on the starting L-His.

Full text of DOI:10.1246/bcsj.64.3741

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