Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases p. 1811 - 1820 (1980)
Update date:2022-08-17
Topics:
Bridgewater, Alan J.
Burch, Robert
Mitchell, Philip C. H.
The activites and selectivities of Mo/C and Mo/Al2O3 catalysts (prepared by impregnating a coconut charcoal and γ-Al2O3, respectively, with ammonium heptamolybdate) have been determined for the reforming of cyclohexane, n-hexane, methylcyclopentane and n-heptane in a microreactor by pulse and flow techniques at 1 atm and 773 K.The Mo/C catalyst was more selective and more stable than the Mo/Al2O3 catalyst.The Mo/C catalyst was more active for dehydrogenation and dehydrocyclisation whereas Mo/Al2O3 was more active for ring expansion, isomerization and cracking.Over Mo/C in the pulse experiments the predominant cracked product was methane.The Mo/C catalyst behaved mainly as a metallic-type catalyst catalysing ring-closure reactions (n-hexane to benzene, n-heptane to toluene) directly and not via a methylcyclopentane intermediate, while the Mo/Al2O3 catalyst had both metallic and acidic functions.The molybdenum catalysts are compared with Pt/Al2O3 catalysts.
View MoreAnhui Xinyuan Technology Co.,Ltd
Contact:0086-559-3515800
Address:No.16 Zijin Rd, Circular Economic Zone, Huizhou District, Huangshan Anhui China
Bejing Famous Pharmaceutical Technology Co., Ltd
website:http://www.peking-pharmacy.com
Contact:86-316-3097308
Address:Hangwang road, Yanjiao Economic and Technological Development Zone, Hebei, 65200,China
Ningbo Hi-tech Zone Nice-Synth Chemical Industry Ltd.
Contact:+86-(574)-81110986
Address:No. 1210, Building 3, Wante Business Centre, Hi-tech Zone, Ningbo
Contact:+86-021-58123769
Address:No.780 of Cailun Road,Zhangjiang Hi-tech Park,Pudong,Shanghai
Contact:86-0555-5136566
Address:Maanshan city, He county Anhui province high-tech zone No.8 Laoxiahe east road
Doi:10.1124/mol.116.107821
(2017)Doi:10.1016/j.steroids.2014.03.011
(2014)Doi:10.1016/j.bmcl.2017.03.049
(2017)Doi:10.1023/A:1022421020644
(2003)Doi:10.1021/j100321a045
(1988)Doi:10.1021/jo50010a003
(1952)
