Journal of the Chemical Society. Chemical communications p. 121 - 122 (1995)
Update date:2022-08-11
Topics:
Crestoni, Maria Elisa
Fornarini, Simonetta
Lentini, Massimo
Speranza, Maurizio
The efficiency (kobs/kcoll) of the gas phase hydride ion transfer from 2,2-dimethylbutane to tert-butyl cation displays a pronounced positive pressure dependence, which suggests significant anchimeric assistance of the methyl groups of 2,2-dimethylbutane adjacent to the departing CH2 hydride in the transition state.
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