Journal of the Chemical Society. Chemical communications p. 859 - 860 (1980)
Update date:2022-08-11
Topics:
Davidson, Iain M. T.
Lawrence, F. Timothy
Ostah, Naaman A.
Dimethylsilylene, generated by photolysis of dodecamethylcyclohexasilane, inserts into the silicon-hydrogen bond in trimethylsilane and pentamethyldisilane with approximately zero activation energy, while insertion into hydrogen chloride requires an activation energy of 28 kJ mol-1; the results for silicon-hydrogen insertion shed some light on the mechanism of the thermolysis of pentamethyldisilane.
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