Chemistry Letters p. 783 - 784 (1995)
Update date:2022-08-10
Topics:
Yasui, Shinro
Shioji, Kosei
Tsujimoto, Munekazu
Ohno, Atsuyoshi
Cation radicals generated from trivalent-phosphorus compounds through single-electron transfer to methylviologen undergo ionic reactions with alcohols or thiols.A kinetic analysis of the reactions has suggested that the reaction of the trivalent-phosphorus cation radicals with alcohol possesses a tighter transition state than that with thiols.
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