Reactivity of cation radicals generated from trivalent-phosphorus compounds in the reaction with methylviolgen: Kinetic analysis

DOI: 10.1246/cl.1995.783

Source and publish data:

Chemistry Letters p. 783 - 784 (1995)

Update date:2022-08-10

Topics:

Authors:

Yasui, Shinro

Shioji, Kosei

Tsujimoto, Munekazu

Ohno, Atsuyoshi

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Article abstract of DOI:10.1246/cl.1995.783

Cation radicals generated from trivalent-phosphorus compounds through single-electron transfer to methylviologen undergo ionic reactions with alcohols or thiols.A kinetic analysis of the reactions has suggested that the reaction of the trivalent-phosphorus cation radicals with alcohol possesses a tighter transition state than that with thiols.

Full text of DOI:10.1246/cl.1995.783

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