Stereoselective Synthesis of Perfluoroalkylated (E,E)-Dienes from Perfluoroalkylated Alkynes. The Synthesis of Fluorinated Analogs of Lepidoptera Pheromones

DOI: 10.1016/0040-4020(95)00752-T

Source and publish data:

Tetrahedron p. 11765 - 11774 (1995)

Update date:2022-08-30

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Authors:

Wang, Zhong

Lu, Xiyan

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Article abstract of DOI:10.1016/0040-4020(95)00752-T

Pd(dba)2 -HOAc catalyzed the isomerization of 1-perfluoroalkyl-1-alkynes to give 1-perfluoroalkyl-(1E,3E)-dienes in good yield and stereoselectivity; the fluorinated analogs of Lepidoptera species sex pheromone attractants were synthesized applying this method.

Full text of DOI:10.1016/0040-4020(95)00752-T

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